Tuesday, December 3, 2019

Nothing but the Truth Essay Example

Nothing but the Truth Essay Such a simple idea. Yet the force that drives it is powerful. Some might say, too powerful. Why, you ask. Because everything depends on the balance of truth. When a simple moment is blown out of proportion, it can lead to catastrophic results. Truth or the lack thereof affects every judgment that has, or ever will be made. Our decisions are clouded by how much of the truth we really know. It really isn’t that much of a wonder that an innocent lie can worm its way into the core of balance, and by slightly upsetting the scales, ruin everything. In Nothing But The Truth, both Philip Malloy and Miss Narwin’s life gets changed after the public begins to interfere with their dismal relationship. However, not all of what occurred was Philip’s and Miss Narwin’s fault. The lie Philip instilled into the system was nurtured and cared for by others, and it took a life of its own. The three biggest components (excluding Philip or Miss Narwin) of their jigsaw of problems were Philip’s parents, the School Administration, and Ted Griffen. These people are the biggest players of the game, because they had the power to use and the ability to administer it. We will write a custom essay sample on Nothing but the Truth specifically for you for only $16.38 $13.9/page Order now We will write a custom essay sample on Nothing but the Truth specifically for you FOR ONLY $16.38 $13.9/page Hire Writer We will write a custom essay sample on Nothing but the Truth specifically for you FOR ONLY $16.38 $13.9/page Hire Writer They should have taken more responsibility and instead of letting the situation run away and get out of hand, they should’ve contained it so that it wouldn’t explode in their faces. Philip’s parents had a huge influence on the outcome of the story. They were the driving force of Philip’s side. Without even thinking about both sides of the story, they automatically started a war-of-sorts against Miss Narwin. Philip’s parents should have listened to what Miss Narwin was saying. They should have paid more attention to the whole story, and should have kept a closer touch with Philip in general. If they had been able to keep a closer eye on the situation, they might have been able to tone it down a bit. Philip’s parents also took their opinion too far. The fact that Philip got suspended simply for singing the national anthem is too unusual for that to be the whole story. Alerting the media and making it a huge deal was just overdoing things. The School Administration is another cause for the outcome. They ought to have stuck with Miss Narwin the whole way, because she was one of their teachers. They shouldn’t have let the world hate her for something that she didn’t do; they should’ve stood up for her because they knew the truth. The administration was all talk and no work. They kept declaring how they couldn’t afford the budget to not pass, but they never tried to do anything about fixing the situation until it was too late. When the superintendent eventually confronted Ted Griffen, it was too late to change anything. If they had been more proactive instead of waiting for the outcome, they might have been able to alter the ending and maybe save the budget too. Although he might not seem important, Ted Griffen was a huge element of this escapade. Because his only motive was to be on the board of education, he didn’t care what consequences would occur, and was willing to go to any extent to reach his goal. He manipulated the situation to his complete advantage. Since he knew that the public didn’t want to pay for the budget, he used the school’s dilemma as his campaign premise, and was able to hurl the situation out of control very easily. Because he appealed to the people’s needs, he could make feeble connections between the situations, and then draw on their agreement to give him votes. Philip’s parents, the Administration, and Ted Griffen have a lot to account for. They were the dynamic influences, the people with opportunities to keep the situation in hand. As a result of bad judgment and planning, they caused Philip to eventually move to Washington Academy and for Miss Narwin to resign. Because they made the wrong the choices, and then the effects of their actions were truly revealed. They didn’t wield their power properly, and both Philip and Miss Narwin suffered.

Wednesday, November 27, 2019

Kayaking free essay sample

The first time I went kayaking was in a very small pond at my friend’s neighbor’s house. I was nervous at first and then when it came time to leave, I didn’t want to get out. Since that time I have only gone kayaking once and that was on Black Creek in Churchville, New York. I have looked at many kayaks and equipment that goes with it. The one kayak that popped out at me the most is the EZG 42 wavesport. The place I would go kayaking is called Black River; it is near Watertown, New York. Kayaks come in different sizes and shapes, but there is one that won me over and that was the EZG 42 wavesport. The reason why I chose the EZG 42 wavesport kayak is because it used for white water and that is what I want to do. I just want to go and have a good time and feel good about it. We will write a custom essay sample on Kayaking or any similar topic specifically for you Do Not WasteYour Time HIRE WRITER Only 13.90 / page The kayak I looked at can be bought used or new and I chose the used price which was $920. The size of the kayak is 6 feet and 6 inches in length which is a good fit for me so I can go down a rushing river. I also chose that kayak because I love the color of it and that it is comfortable at the same time. When you are going down a rushing river it is important to have kayak with you so you don’t go to the bottom of the river. Paddles are a good piece of equipment that you can have on you when you are in a kayak. The paddle that I chose to go along with the kayak is a Werner twist straight shaft paddle. The reason why I chose that paddle was because both ends do not line up which gives it a great power and responsiveness so I can actually paddle and steer faster. I chose this paddle because it is made out carbon fiber that makes it light and stronger. The shafts on the paddles will enhance the energy during each stroke you take. When the blades are smaller in diameter they can give a more powerful catch then longer blades do. The paddles are not just the thing that I needed so I could go on a trip down the river. The sprayskirt that I chose was the Adventure GTX 7. 0 because it is waterproof, so that there will not be any water going into the kayak. The sprayskirt deck will keep the water away, and preventing puddles from forming on it. The skirt also has a really good seal seam on it making it impossible to get water in the kayak. The sprayskirt I looked can also be adjustable to fit all sizes and it has a Velcro on the waist allowing it to be able to remove to become suspenders if necessary. The reason why I chose these models out of the rest was because they were the cheapest ones I could find and they don’t fall apart easily. The helmet and lifejacket are the most important pieces of equipment because they will save your life when you are in a river. The helmet and lifejacket that I chose are called the Shred Ready AHM Livery Helmet and the Extrasport Universal PFD. The reason why I chose those two was because they will help keep you safe if you go under in rushing water. The helmet will help protect your head from hitting something and getting knocked out. The reason why I chose those models was because the lifejacket will help you stay above water if you get knocked out of your kayak. One of these days I want to actually go white water kayaking with a bunch of people. Before I do go kayaking in a rushing river I want to get better and learn how to flip back over while under water. If I learn how to do that I am pretty sure I can go on any river. The most important thing I have learned was to have fun and learn how to flip a kayak back over while in it.

Saturday, November 23, 2019

Special Stains Laboratory Report

Introduction Special Stains Laboratory Report IntroductionMethodMasson’s TrichromeCongo RedDiscussionReferencesRelated Introduction Staining is a technique that is used to diagnose or study the morphology of abnormal cells such as cancerous cells by highlighting the structural components of a tissue (Bancroft and Gamble, 2008). Staining provides a contrast between different structures in a tissue specimen and allows its examination under a light microscope (Cook, 2006). Haematoxylin and eosin (HE) is a routine stain that is used to microscopically diagnose a vast majority of specimens in which the haematoxylin stains the nuclei, whereas the eosin is used to stain cytoplasm and other extracellular materials (Bancroft and Cook, 1995). According to Slauson and Cooper (2002) special stains are histochemical stains that react with known substances in the tissue. Mohan (2005) explains that special stains are required in various circumstances, where the pathologist needs to demonstrate certain constituent of the cells or the tissue to confirm the diagnosis by etiologic, histogenic and pathogenic components. This techniq ue is called special because they are not a routine stain that is performed on a tissue specimen, instead they are used in addition to HE stained sections (Bancroft and Gamble, 2008). Special stains can identify the presence and abundance of any specific class of molecules in a tissue specimen for example periodic acid-Schiff (PAS) reaction is used to identify carbohydrate substances such as glycogen (Slauson and Cooper, 2002). Other examples include Toluidine blue stain which is used to stain mast cell granules, Perl’s stain demonstrates iron in haemochromatosis, Ziehl-Neelsen stains mycobacteria and Giemsa staining is used to identify Helicobacter Pylori and Giardia organisms (Slauson and Cooper, 2002 and Bass et al., 2005) Masson’s trichrome (MT) and Congo red are the two main special staining methods used in pathology laboratories. Connective tissues consist of cells such as collagen fibres, elastic fibres, and glycosaminoglycans that are scattered within an extracellular matrix (Starr et al., 2011). These cells are distinguished by using a combination of dyes to stain different structures in various different colours (Starr et al., 2011). Masson’s trichrome is used to express collagen in tissues and involves staining with three different sized dyes to stain three diverse tissue densities (Cook, 2006). MT staining produces three distinct colours as the name suggests; nuclei and other basophilic structures are stained black with iron hematoxylin; collagen is stained green or blue depending on aniline light green or aniline blue; and cytoplasm, muscle, erythrocytes and keratin are stained bright red with Biebrich scarlet stain (Young et al., 2006). Since erythrocytes are the densest as the y are packed with haemoglobin, and less porous tissues they are stained with the smallest dye molecule, the intermediate cytoplasm and muscles cells are stained by the intermediate sized dye and the collagen is stained with the biggest dye (Bancroft and Gamble, 2008). However, it has also been suggested that the acid dye which is the Biebrich Scarlet, first stains the tissue as it binds to its acidophilic elements (Carson, 2001). Subsequently, the tissue is treated with phosphomolybdic/phosphotungstic acids so that the less permeable components retain the red colour, whereas it is diffused out of the collagen fibers causing it to bind with the aniline blue or aniline light green (Bancroft and Gamble, 2008). Young et al., (2006) describes that in addition to the use MT stain in assessing the degree of fibrosis, it is also used to evaluate portal tract structures such as the bile ducts, arteries and veins in inflamed liver According to Romhanyi (1971) (cited in Bely, 2006) Congo red is a special stain that is highly specific and a sensitive method for early diagnosis and recognition of amyloidosis.   Cook (2006) states that Congo red is used as the preferred method to identify amyloids in most laboratories on formalin fixed, paraffin embedded tissue of patients with amyloidosis. Kiernan (2007) describes that amyloid is an intercellular material that varies in its composition and is deposited in tissues such as heart, muscle, kidneys, spleen, liver and brain, deposits differ in their composition. Rubin and Strayer (2008) explains that Congo red stain has a linear shaped molecule which helps it to bind to the ÃŽ ² pleated sheet structure of the amyloid through non-polar hydrogen bonds, giving it a red colour. Sen and Basdemir (2003) states that Congo red fluorescence (CRF) is another method that examines the amyloid deposits stained with Congo red under polarized light which shows a red-green birefring ence and according to Rocken and Eriksson (2009) this is the gold standard for diagnosing amyloid. During this experiment special stain techniques were used to analyse specific tissue elements Aims To identify fibroids in uterine tissue section using Masson’s trichrome stain To identify amyloid in spleen tissue section using Congo red stain To discuss advantages of special stains To use special stains to identify important diagnostic features of the tissue To understand the mechanism used by special stains Method Masson’s Trichrome The formalin fixed and paraffin-embedded uterine tissue section was deparaffinized and rehydrated through 100% alcohol, 95% alcohol, and 70% alcohol.   The section was washed in distilled water and then stained in Weigert’s iron hemotoxylin working solution for 10 minutes. It was then rinsed in running warm tap water for 10 minutes and then washed in distilled water. The next step was to stain the uterine tissue section in Biebrich scarlet-acid fuchsin solution for 15 minutes, and then it was washed using distilled water. It was then differentiated in phosphomolybdic – phosphotungstic solution for 15 minutes or until collagen was not red. The tissue section was then transferred directly (without rinsing) to aniline blue solution and stained for 5-10 minutes. Afterwards the tissue section was rinsed briefly in distilled water and differentiated in 1% acetic acid solution for 1 minute. It was then washed in distilled water and dehydrated very quickly through 95% ethyl a lcohol, absolute ethyl alcohol (to wipe off Biebrich scarlet-acid fuschin staining) and then cleared in xylene. The section was then mounted with resinous mounting medium. Finally the slide was examined under the light microscope. Congo Red The spleen tissue section was deparaffinized and hydrated to distilled water. The section was then stained in Congo red working solution for 10 minutes and rinsed in distilled water. It was then quickly differentiated (5-10 dips) in alkaline alcohol solution and rinsed in tap water. The section was then counterstained in Gill’s haematoxylin for 10 seconds and rinsed in tap water for 2 minutes. Following that, the section was dipped in ammonia water (made by adding a few drops of ammonium hydroxide to tap water and mixing it well) for 30 seconds or until the sections had turned blue. It was then rinsed in tap water for another 5 minutes and dehydrated through 95% alcohol, and 100% alcohol. The section was cleared in xylene and mounted with mounting medium. The slide was then examined under a light microscope. Fig 1: Normal uterine tissue stained with Masson’s trichrome viewed under 10 x 10 microscopic magnification Fig 2: Fibroid uterine tissue stained with Masson’s trichrome viewed under 10 x 10 microscopic magnification The microscopic slide (Fig. 1) shows a normal uterus tissue that was stained with Masson’s trichrome, which showed the nuclei stained black, smooth muscle stained red and the collagen fibres stained blue.   Figure 2 shows a uterus tissue specimen stained with Masson’s trichrome that revealed excessive amount of collagen stained in blue, smooth muscle stained red and nuclei stained black.    Fig 3: Spleen tissue stained with Congo red showing amyloid deposits under 1010 microscopic magnification Fig. 4 Spleen tissue stained with Congo red adapted from Stevens and Lowe, (2000) Discussion Norwitz and Schorge   (2006) states that fibroids also referred to as Leiomyomata, are benign tumours of the myometirum of the uterus   that is mainly composed of smooth muscle and extracellular fibrous material such as the collagen, Fibroids do not   invade surrounding tissues or organs and they can occur in different locations within the uterus (Lark, 1996). The symptoms include heavy periods, frequent urination, constipation, bloating and backache (Tulandi, 2003) Masson’s trichrome was used to stain the uterus tissue (Fig. 1) which showed the collagen stained in blue, smooth muscle and erythrocytes stained red and the nuclei appeared black. MT stain revealed that the normal uterus tissue (Fig. 1) had a small amount of collagen present whereas the other uterus tissue (Fig. 2) showed an elevated amount of collagen stained in blue which suggested fibrosis. MT is an advantageous technique in medicine as it allows comparing the degree of fibrosis before and after the treatment biopsies to show if the treatment has been effective and successful. It is a routine stain for kidney and liver biopsies and this can be used on paraffin fixed sections as well as on frozen sections. Kambic et al., (1986) describes that there are different types of collagen and their organization is better shown using Sirius red with polarized light. Sirius red is a hydrophilic dye, in which type I collagen appears orange or red whereas type III collagen appears green (Kumar, 2005). Congo red was used to stain a spleen tissue section where figure 3 showed amyloid deposits in pink and nuclei in blue. Fig. 4 revealed a high amount of amyloid deposits in pink which suggested amyloidosis that is the disorder caused by abnormal deposition of intracellular or extracellular insoluble amyloid which changes the normal tissue function (Stevens and Lowe, 2000). Special stains is an important tool for pathologists   as it allows to the microscopically view and identify cells, tissues and microorganisms, providing an alternative to immunohistochemistry, flow cytometry and various other diagnostic techniques. References Bancroft, J. D. Gamble, M.   (2008).   ‘Theory and practice of histological techniques’.   [Online].   (6th ed).   Philadelphia, PA : Churchill Livingstone/Elsevier.   Available from: http://books.google.co.uk/books?id=Dhn2KispfdQCprintsec=frontcoverdq=Theory+and+practice+of+histological+techniqueshl=enei=ifGETZKEPcWwhAfSvPW_BAsa=Xoi=book_resultct=resultresnum=1ved=0CC8Q6AEwAA#v=onepageqf=false.   [Accessed 7th March 2011]. Bancroft. J. D. Cook, H. C.   (1995).   ‘Manual of histological techniques and their diagnostic application’.   Edinburgh [u.a.] : Churchill Livingstone. Bass, P., Burroughs, S. Way, C.   (2005).   ‘Systematic pathology : a clinically-orientated core text with self assessment’.   Edinburgh : Elsevier Churchill Livingstone. Bely, M. (2006). Histochemical differential diagnosis and polarization optical analysis of amyloid and amyloidosis TheScientificWorldJournal. 6, p.154-168. Carson, F. L.   (2001).   ‘Histotechnology : a self-instructional text’.   (2nd ed).   Chicago : ASCP Press. Cook, D. J.   (2006).   ‘Cellular pathology : introduction to techniques and applications’.   (2nd ed).   Bloxham: Scion Publishing Limited. http://onlinelibrary.wiley.com/doi/10.1046/j.1440-1827.2003.01513.x/abstract Kiernan, J. A.   (2007).   ‘Histological and histochemical methods’.   (4th ed).   Cold Spring Harbor (N.Y.) : Cold Spring Harbor Laboratory Press. Mohan, H.   (2005).   ‘Essential pathology for dental students’.   [online]. (3rd ed).   New Delhi : Jaypee Brothers.   Available from: http://books.google.co.uk/books?id=HmkTtLyxXF8Cprintsec=frontcoverdq=essential+pathology+for+dental+studentshl=enei=xRCCTaiHMs24hAezp6G8BAsa=Xoi=book_resultct=bookthumbnailresnum=1ved=0CDAQ6wEwAA#v=onepageqf=false. [Accessed: 11th March 2011]. Odze, R. D. Goldblum, J. R.   (2009).   ‘Surgical pathology of the GI tract, liver, biliary tract and pancreas’.   [Online].   (2nd ed).   Philadelphia, PA : Saunders/Elsevier.   Available from: http://books.google.co.uk/books?id=8ITX093f1j0Cpg=PA1143dq=Masson%27s+trichrome+staining+in+liverhl=enei=OB2GTYuVLYuqhAfJ_6m8BAsa=Xoi=book_resultct=book-thumbnailresnum=2ved=0CDgQ6wEwAQ#v=onepageq=Masson%27s%20trichrome%20staining%20in%20liverf=false.   [Assessed 16th March 2011] Rocken, C. Eriksson, M. (2009). Amyloid and amyloidoses Der Pathologe. 30, (3), p.182-192. Rubin, R. Strayer, D. S.   (2008).   ‘Rubin’s Pathology : clinicopathologic foundations of medicine’.   [Online].   (5th ed).   Philadelphia [u.a.] : Lippincott Williams Wilkins.   Available from: http://books.google.co.uk/books?id=kD9VZ267wDECpg=PA990dq=mechanism+of+congo+red+stainhl=enei=ADGFTcSQDZGJhQf-n5iuBAsa=Xoi=book_resultct=book-thumbnailresnum=4ved=0CEUQ6wEwAw#v=onepageq=mechanism%20of%20congo%20red%20stainf=false.   [Assessed 7th March 2011]. Sen, S. Basdemir, G. (2003). Diagnosis of renal amyloidosis using Congo red fluorescence Pathology international. 53, (8), p.534-538. Slauson, D. O.   Cooper, B. J.   (2002).   ‘Mechanisms of disease : a textbook of comparative general pathology’.   [Online].   (3rd ed).   St. Louis, MO. [u.a.] : Mosby.   Available from : http://books.google.co.uk/books?id=vRhtM0UMUh4Cpg=PA5dq=special+stainshl=enei=-vSETaMeqJKEB83RwccEsa=Xoi=book_resultct=book-thumbnailresnum=1ved=0CCoQ6wEwADgK#v=onepageq=special%20stainsf=false.   [Accessed 4th March 2011]. Young B., Lowe, J. S, Stevens, A. Heath, J. W. (2006).   ‘Wheater’s functional histology : a text and colour atlas’.   (5th ed).   Edinburgh : Churchill Livingstone Tulandi, T.   (2003).   ‘Uterine fibroids : embolization and other treatments’.   [Online].   Cambridge : Cambridge University Press.   Available from: http://books.google.co.uk/books?id=fZ8eha5yIfcCprintsec=frontcoverdq=fibroidshl=enei=oyOGTfnfMJGGhQeY_92_BAsa=Xoi=book_resultct=book-thumbnailresnum=7ved=0CGAQ6wEwBg#v=onepageqf=false.   [Assessed 15th March 2011]. Stevens, A. Lowe, J.   (2000).   ‘Pathology’.   (2nd ed).   Edinburgh [u. a.] : Mosby Starr, C., Evers, C. A. Starr, L.   (2011).   ‘Biology : concept and applications’.   [Online].   (8th ed).   United States : Cengage Learning.   Available from: http://books.google.co.uk/books?id=_16xbB2Py_UCpg=PA454dq=connective+tissuehl=enei=zYeITdaEAsywhAf61cm6Dgsa=Xoi=book_resultct=book-thumbnailresnum=10ved=0CFYQ6wEwCTgK#v=onepageq=connective%20tissuef=false.   [Assessed 8th March 2011]. Lark, S. M.   (1996).   ‘Natural treatment of fibroid tumors and endometriosis : effective natural solutions for relieving the heavy bleeding, cramps and infertility that accompany these common female problems’.   New Canaan, Conn : Keats Pub. Norwitz, E. R. Schorge, J. O.   (2006).   ‘Obstetrics and Gynaecology at a glance’.   (2nd ed).   Malden, Massachusetts : Blackwell. Kumar, R. K. (2005). Morphological methods for assessment of fibrosis Methods in Molecular Medicine. 117, p.179-188. Kambic, H. E., Kantrowitz, A. Sung, P.   (1986).   ‘Vacular graft update : safety and performance, a symposium’. [Online].   Philadelphia, PA : ASTM.   Available from: http://books.google.co.uk/books?id=NU0cVwIPk_oCpg=PA162dq=limitations+of+collagen+stainhl=enei=AEKLTcmzMsmYhQe1hJHEDgsa=Xoi=book_resultct=resultresnum=10ved=0CFsQ6AEwCQ#v=onepageqf=false.   [Assessed 20th March 2011].

Thursday, November 21, 2019

Marketing Image differentiation competitive advantage Essay

Marketing Image differentiation competitive advantage - Essay Example It should be noted that in this type of differentiation strategy, the product is not tangibly different from its competitors. The marketer's primary function, then, is the addition of intangible features which would enhance the image and position of the product in the market. Tangible differentiation is much more apparent and easily identified than intangible ones. In case of toothbrushes, Colgate and Oral B are tangibly different. Oral B toothbrushes are distinctive because of the red dye in the center bristles which fades and tells customers when they need a new toothbrush. On the other hand, Colgate offers its revolutionary toothbrush that focuses on overall hygiene with its tongue cleaner. Intangible differentiation can best seen in the laptop market. It should be noted that some notebooks offered by Hewlett-Packard and Apple Computers are the same in terms of memory, connectivity, battery life, etc. However, customers are willing to pay a premium for a Mac because it is marketed as an upscale product while HP is for the mass market. The price of the notebooks together with their images in the market succeeds in creating intangible differences for the product. Extreme examples of the two products which are tangibly the same but are differentiated in the market

Wednesday, November 20, 2019

Module 6 Essay Example | Topics and Well Written Essays - 500 words - 1

Module 6 - Essay Example It is believed that there are certain places considered as sacred spaces where the kami communicate with people. These places are usually located near waterfalls, trees and mountains, rivers, and other unusual natural formations. In these places, shrines are built to house the kami where the sacred space separates them from the ordinary world. Sacred spaces also exist in the homes where the kamidana or home shrine is designated. The shrine and the home shrine are therefore treated with the utmost respect, and this is evident in the architecture of the edifice. A large gate called tori, with a distinctive design fronts kami shrines, exhibiting two upright bars and two crossbars that indicate the separation of the sacred from the common space. Aside from this several real and symbolic barriers mark the sacred space, such as statutes of protection, ropes and fences. The shrines have distinctive parts such as the public hall of worship (haiden), the hall of offerings (heiden), and the innermost portion which comprises the worship hall reserved for the high priest (honden). It is in the honden where the symbol of the enshrined kami is situated. http://it.spcollege.edu/flashapplications/accessibleYouTubePlayer/index.htm?swfWidth=480&swfHeight=358&videoWidth=480&videoHeight=270&srtFile=http://it.spcollege.edu/srt/HUM2270_KevinMorgan/Hum2270_Mod6_EarlJapArtCult_TradJapArch.srt&youtubeURL=http://www.youtube.com/watch?v=VVnQvhS4vRs The video chosen for review describes how Japanese dwellings are constructed. It is interesting to note that the traditional Japanese home is constructed of wood and light materials and seldom have solid walls. There are also no permanent partitions, only temporary dividers, typically free-standing folding screens made of paper that are set up when the need to segregate spaces arises. Occasionally, there are also sliding doors which are installed along wooden

Sunday, November 17, 2019

The Formation of Diels-Alder Reactions Essay Example for Free

The Formation of Diels-Alder Reactions Essay The Diels-Alder reactions consist of a reversible dienophile and diene all in a one-step reaction initiated by head. These reactions form a six membered ring with at least one pi bond and two sigma bonds, making the reaction exothermic. The goal of the first part of these experiments is to make products that have a greater aromatic stabilization. In 1928, Otto Paul Hermann Diels and Kurt Alder first documented this type of reaction, hence the name Diels-Alder reactions. Their reaction is one of the more useful reactions done in chemistry because it does not require very much energy in order to make the cyclohexene ring and the result can create four stereo centers, making it compatible for a variety of functional groups which still has double bonds in the products. Dimethyl Tetraphenylphthalate. Tetraphenylcyclopentadienone (0.100g), dimethyl acetylene-dicarboxylate (0.1mL), and nitrobenzene (1mL) was placed into a reaction tube with a boiling stick. The reaction was heated until the purple solution turns tan and refluxed. Ethanol(3mL) was stirred in after the solution was warm, and placed in ice. The solid was vacuum filtered, washed with ethanol, dried and weighed. Hexaphenylbenzene. Tetraphenylcyclopentadienone (0.100g) and diphenylacetylene (500mg) was placed in a reaction tube and loosely capped. The solid was heated to reflux with a sad bath until the solid turned a brown color. The tube was shaken gently to bring about white solids at the bottom of the reaction tube. Diphenyl ether(2mL) was added and heated until the solid dissolved. The reaction tube was cooled again and had toluene(2mL) added then placed in ice. The product was vacuum filtered, washed with toluene, dried, and weighed. Tetraphenylnaphthalene. Tetraphenylcyclopentadienone(0.500g), glyme(3mL), and a boiling chip was added to a reaction tube. Isoamyl nitrite(0.35mL) was added via syringe to reaction tube and heated to reflux for 2-5 minutes. Anthranilic acid(0.250g) and glyme(2mL) was dissolved in a separate reaction tube, then added to refluxing solution dropwise via pipette. The color changed from brown to yellow after 5 minutes, and then heat was added for another 2 min. The mixture was shaken and cooled to room temperature. Ethanol(10mL) and saturated sodium bicarbonate(5mL) was added to the solution and shaken to allow solid to form. The solid was vacuum filtered, washed two times with cold water, then two times with cold ethanol. The product is then recrystallized with nitrobenzene/ethanol, filtered, dried and weighed. The melting point was recorded. Triptycene. Anthracene(0.400g), isoamyl(0.4mL), glyme(4mL) and a boiling chip was placed into a reaction tube and heated using a sand bath. Anthranilic acid(0.520g) was dissolved into glyme(2mL). Anthranilic acid solution was added deopwise via pipette into refluxing apparatus over a twenty minute period, followed by isoamyl nitrite(0.4mL). the mixture was refluxed for an additional ten minutes, then cooled. Ethanol(5mL), 3 M sodium hydroxide solution(10mL) was added to solution. Mixture was filtered and rinsed with cold ethanol, then cold water, then took the crude weight of the product. The solid was placed into a round bottomed flask where maleic anhydride(0.200g) and triglyme(4mL) was added. The mixture was refluxed for five minutes, and cooled. Ethanol(2mL) and 3 M sodium hydroxide solution(6mL) was added to solution. The mixture was filtered and rinsed with cold ethanol and cold water, recrystallized with methanol, filtered, dried and weighted to get final product.

Friday, November 15, 2019

Factors Affecting Buildability of Building Designs

Factors Affecting Buildability of Building Designs Buildability is increasingly become a major requirement in building construction practice. The aim of buildability is use to improve the efficiency of overall building process by developing construction sensitive designs. Nowadays, in Malaysia construction industry, there have facing a lot of problem that will impede the project to process smoothly. In this research, it will highlight what buildability is. Through this we can deeply understand what buildability is and how important it was in the construction industry. Moreover, in this research, we wish to find out and identify the buildability attributes in building design in Malaysia construction industry. There are many buildability attributes have affecting in the building design. If the constructions proceed without a good buildability management, it will bring many problems to the project. So in this research, besides that identifying the buildability attributes, we also wish to find out the importance level for each of these attributes. AIM This report are aim to find out the factors that affect buildability of building design in the Malaysian construction industry. OBJECTIVE In order to achieve the aim of the report, the following are the objectives of this research To study what is buildability and factors may affect it in building design To find out and identify the buildability attributes in building design in the Malaysian construction industry To measure the level of importance of different buildability attributes Research Methodology Literature Review The purpose of the literature review is given us to understanding what buildability in the construction industry is and how important it was. This research methodology may include definitions, ideas and practices of related topics. Besides that, we can study and review to the relevant books, journals, internet and etc., as known as secondary data, that related to the topic buildability. Through those review sources, the important point will be noted down and convenience for us to writing the literature review. The below are showing that the literature search that will be carried out:- Define the definition of buildability/ constructability Define the principle and concept of buildability/ constructability Determine the factor affecting buildability in building design in construction Determine the building attributes and the level of importance for each attribute Questionnaire Questionnaire is recommended as one of the research method, because it is easier for analyzing the data, economical and the hypothesis can be tested. Questionnaire is a research instrument consisting of a series of questions and/or in difference grouping for the purpose of gathering the information from respondents. To gain more information of this research, copies of questionnaire will be sent out to the construction companies and they are needed to express their opinions based on their experience. In this questionnaire, there are empty spaces provide for the respondents to giving their comment or suggest other building attributes which are not included. This questionnaire will target to the professionals such as architect, engineer, project manager, quantity surveyor and others in the contractor industry firm in Malaysia. From the research title, to determine the level of importance of buildability attributes in this research, the classification of the rating scales is used. The questionnaire is based on LIKERT SCALE format. It is a widely used instrument in measuring opinions. A likert item is simply a statement which the respondent is asked to evaluate according to any kind of subjective or objective criteria and generally the level of agreement or disagreement is measured. 5 point likert scale being used as it may produce slightly higher mean scores relative to the highest attainable score. This will be carried out in the final stage of research methodology. The results/ comments get from the respondents will be analyze and present in table or graph in order to provide a clearer view of overall research with writing up the contents of the dissertation. Besides this, analysis and interpretation would be done to gather all the information and data. DISSERTATION ORGANIZATION Chapter 1- Introduction Chapter 1 provides an introduction of the chapter that giving a brief about our proposal. In this chapter it includes introduction/ background, problem statement, aim, objectives, research methodology and working program for the dissertation. Chapter 2 Literature Review Through the review of literature/ articles related to our research topic the important point will be written in this chapter. Journals, books and information from the internet will be the source of the information or data to doing this buildability title dissertation. This chapter are aim to provide a main picture of the knowledge to us before the research is carried out. Chapter 3 Research Design and Methodology Questionnaire will be designed based on the objective and information that we want to find out. These questionnaires will be sent to different construction industry companies in Malaysia to collect data to conduct next step of dissertation. Chapter 4 Data Analysis and Results Discussions The collected information from the respondents will be evaluated and analyzed in table or graph with explanation. Chapter 5 Conclusions This chapter will conclude and recommend the overall results of the survey for further research. REFERENCES Crowther,.P. Design For Buildability and The Deconstruction Consequences, Design for Deconstruction and Materials Reuse, CIB Publication 272. Lam, P.T.I., Wong, F.K.W., Wong, F.W.H. 2007. Building features and site-specific factors affecting buildability in Hong Kong, Journal of Engineering, Design and Technology, Vol 5, No 2. Mydin S.H., Zin R.M., Majid M.Z.A, Zahidi M. and Memon A.H. 2011. Buildability Attributes at Design Phase In Malaysian Building Construction, International Journal of Sustainable Construction Engineering Technology, Vol. 2, Issue 1. Wong, F.W.H, Lam, P.T.I, Chan, E.H.W. and Wong F.K.W. 2006. Factors Affecting Buildability of Building Design, Canadian Journal of Civil Engineering, 33.7, pg 79 CHAPTER 2 LITERATURE REVIEW INTRODUCTION Buildability or constructability has a huge area of study and it was very important in a construction industry. The aim of these literature reviews are to study and highlight the area that the buildability attributes that may affect the building design in Malaysia construction industry. The first reviews that will focus in this chapter are definition of buildability, then coming up with the principles and concepts of buildability which have defined by different countries. Moreover, this review also focuses on the factors that may affect the buildability by identify the buildability attributes in building design. BUILDABILITY/CONSTRUCTABILITY DEFINITION OF BUILDABILITY Since the buildability is important in the construction industry, so there are many researchers from different countries has identified and defined buildability based on their studies. Based on the several articles study and resources, it found that the one of the widely definition that can be accepted which is define by the Construction Industry Research and Information Association (CIRIA), 1983, it stated that the buildability is the extent to which the design of a building facilitates ease of construction, subject to the overall requirements for the completed building (Wong, Lam, Chan and Wong, 2006B.p. 796). Besides the definition defined by CIRIA, there also have another definition which was founded with specific aim of improving the construction total quality management and the overall cost effectiveness and defined as constructability is the effective and timely integration of construction knowledge into the conceptual planning, design, construction and field operation of a project to achieve the overall project objectives in the best possible time and accuracy at the most cost-effective level by Construction Industry Institute (as known as CII) in year 1986 (Wong, et.al, 2006B.p. 796). According to The Construction Industry in Australia (CIIA), Griffith and Sidwell (1997), has defined constructability as a system to integrate if construction knowledge in the project delivery process and balancing the various project and environmental constraints to achieve the project goals and building performance at the optimal level.(Wong, et.al, 2006B.p. 796) Buildability Performance Research Group (BPRG), Chen and McGeorge (1994), defined buildability as the extent to which decisions, made during the whole building procurement process, ultimately facilitate the ease of construction and the quality of the completed project which buildability as a management to goals the project by recognize the factors affected the project (Eng, 2002.p. 117). In the other hand, there are other researchers have derived their own definitions based on their studying in buildability, such as:- Ferguson (1989); buildability was defined as the ability to construct a building efficiently economically and to agreed quality levels from its constituent materials, components and sub-assemblies (Wong, et.al, 2006B.p. 796.) Williams (1982); buildability was defined as the most economic and efficient way of putting a building together.(Yang, 2004) Illingworth (1984); buildability was defined as a design and details which recognize the assembly process in achieving the desired result safety and at least cost to the client.(Yang, 2004) In year 1996, Moore has modified the definition defined by Illingworth as a design philosophy, which is recognizes and addresses the problems of the assembly process in achieving the construction of the design product, both safety and without resort to standardization or project level simplification.(Yang, 2004) Lueprasert (1996), constructability has defined as an important characteristic of structural design and site conditions of construction project which determines the level of complexity of executing the correlative structural assembly tasks.(Yang, 2004) Moreover, there are few researchers believed that constructability are significantly different with buildability. The differences between buildability and constructability are that buildability is a design-oriented concept but constructability is concern the whole project processing. But also have some researchers thought that there are no difference between buildability and constructability, the only is buildability is usually used in UK and constructability is often used in USA. (Yang, 2004) PRINCIPLES AND CONCEPTS OF BUILDABILITY According to Eng, (2002, p. 112), Buildability or Constructability has been used and evolved in the construction management in the late 1970s in United Kingdom, but its potential was not been fully exploited in construction industry at the time. Nowadays, buildability is increasingly become an integral part of the construction industry in many countries because it was a technique used to manage the construction process during the pre-construction stage. According to Low et.al, (2008), buildability aim is to ensure the impacts of design details are recognized and considered in the earlier stage to reduce and/or prevent errors, delays and allows a cost control to the overall project others. Together with this, it will enhance the productivity and competitiveness of the industry. Moreover, Low study also stated the summarized of buildability principles that defined by some researchers such as Adams (1989), Ferguson (1989), Gray (1984), Griffith and Sidwell (1995), Tatum (1987) and other s as shown as below:- Efficiency and economical building production; to ensure efficient and economical production of a building, a logical organization of the sequence of assembly is necessary. The building organization must ensure continuity of construction work by having food management due to labors, machineries and materials delivery to achieve this principle (OConnor, 1985). Simplicity; this principles saying that the designers of the project must try to produce the simplest possible details compatible with the overall requirement for the building especially for the buildings group of elements (Ferguson, 1989; Bishop, 1985). Tolerance Level; the building design should recognize its tolerances which are normally attainable under site conditions. Different the materials and components used on site have its different composition and different jointing methods required. Therefore, practical level of tolerance adopted is necessary for the materials and components (Ferguson, 1989). Innovation; use any innovative ideas that can enhance the buildability of a project. The contractor should try to bring in new machineries or methods of working that can improve the productivity and allow construction process more efficiency. Before bring in the ideas, consideration of the level of skills available in industry is required. (Tatum, 1987). Proper scheduling; a good scheduling of works may allow construction proceed smoothly and right on track. The construction sequence should be practical to allow for a continuous flow of work to minimize delays of works (Gugel and Russell, 1994). Repetition and standardization; to reduce time consuming for constructions, the building elements should be design that encourages appropriate repetition and standardization, it may help to reduce cost, risk and error by using readily and standard items in construction (Adams, 1989; Ferguson, 1989). Participation and communication; project team members with relevant knowledge should be encourage to participate all level of construction. They can give their opinion and suggestion during early planning stage to reduce problem in future. Clear project information should be planned and coordinated to suit the construction process and facilitate the best possible communication and understanding on site (Fischer and Tatum, 1997). Avoid damage by subsequent works; the design should enable the works that carried out will not have risk of damage due to adjacent finished elements and with minimum requirements for special protection. This would reduce the need for return visits to site to repair damage. By doing few times checking to the completed works is better to reduce the project completion period (OConnor and Tucker, 1986). (Source: Low et.al, 2008) McGeorge and Palmer (1997) have identified that buildability and constructability is the only management concept to have been designed and developed by the construction industry (Eng, 2002). This is because they think that the separation of designs and construction processes is unique to the construction industry. Eng also mentioned that the report in early 1960s, division between the process of design and construction was recognized as contributing to inefficiencies throughout the construction industry. (Eng, 2002).Emmerson (1962) has identified that insufficient documentation before tender, inefficient pre-contract design procedures and lacks of communication among the architects, consultants and contractors appointed are the factors that cause the problem occurred (Eng, 2002). Moreover, Banwell, (1964) suggested that the contractor who is too far from the design stage for his specialized knowledge can be participate in traditional contracting situation. (Eng, 2002.p. 111).In the o ther hand, Banwell report also highlighted that the complexities of modern construction and its requirement for specialized techniques demand that the design process and the construction stage should not be regarded as separate fields of activity. (Eng, 2002.p. 111) EVOLUTION OF BUILDABILITY/CONSTRUCTABILITY CONCEPT Through different groups of researchers, a number of stages in the evolution of the buildability or constructability concept are been identified and related to research efforts in different parts (Eng, 2002). According to Eng (2002) study, it shows the groups of researchers from different countries that have evaluated the evolution of buildability/constructability, which are: Construction Industry Research and Information Association (CIRIA); UK Construction Industry Institute (CII); USA Construction Industry Institute of Australia (CIIA) Building Performance Research Group (BPRG); University of Newcastle in Australia In the early research taken by CIRIA and UK researches, they regarded that buildability is problem that arose from the division between builders and designers; led researchers to focus on technical issue and site and construction planning (Gray, 1983; Adam, 1989; Ferguson, 1989). (Eng, 2002.p. 112) Besides that, Eng stated that most industry researchers and commentators are tended to see buildability as a function that is within the influence or control of the designer. Illingworth (1984) has suggested that the problem of buildability was become deteriorate because the designers and professional team are resented contractors involve and giving their opinions during the design stage.(Eng, 2002.p. 112) In addition, CII had used industry case studies to investigate the constructability problem in construction industry to allow the researchers to understanding the issues. This carried out the understanding of different stages of project life cycle which would relate to different issues in constructability (Eng, 2002). Furthermore, CIIA also used the case studies to enable a holistic perspective to be maintained. CIIA have proposed 12 principles would be relevant with different emphases due to the different project life cycle. For BPRG at University of Newcastle in Australia, they started with conceptualize the buildability problem as one that derived from a complex system and they proposed that the concepts of buildability is needed to recognize the factors in a project environment which may affected in the design process, construction process and the link between them (Eng, 2002). CIRIA RESEARCH IN BUILDABILITY The definition of buildability defined by CIRIA has shown at the above. Though that we know that CIRIA definition is focused between designs and construction; the factors has been implied which are solely within the influence or control of the design team those have a significant impact on the ease if construction of a project (Eng, 2002). The concept was recognized as an issue within an integrated design management context. A good buildability are formed based on a building design, structure or other which had been consider in the construction phase with emphasis on the method of construction, activities, sequence of works and way incorporated into the overall design (Eng, 2002). In additional, Eng study had showing the 16 guiding principles for achieving buildability which was identified and developed by Adams (1989), CIRIA, as below:- Investigate thoroughly Consider accessibility at the design stage Consider storage at design stage Design for early enclosure Design for minimum time below ground work Suitable materials use Consider for the local skill available Design for simple assembly Plan for maximize repetition and standardization Maximize the use of plant Allow for sensible tolerances Allow for a practical sequence of operations Plan to avoid change to work Avoid return visits on site; do it right in first time Safe construction design Clearly communication (Source: Adam, (Eng, 2002)) CONSTRUCTABILITY DEVELOPTMENT BY CII According to Eng (2002), has mentioned that CII used case studies to identify different of requirements for the planning stage (Tatum et.al, 1986), engineering and procurement phases of a project (OConnor et.al., 1986) and improvement of constructability that able to make during field operations (OConnor and Davis, 1988). In additional, they had identified and presented 6 concepts for the planning stage, 7 concepts for the design and procurement phase and 1 for field operations phase which showing below:- Conceptual Planning Stage Basic design approaches consider major construction methods Constructability programs are an integral part of project of project implementation plans Project planning requires construction knowledge and experience Early construction involvement in the development of contracting strategy Project schedules are construction sensitive Site layouts show efficient of construction Design and Procurement Stage Design for accessibility, materials and equipment Design for construction in adverse weather and remotes locations Design and procurement schedules are construction sensitive Design to enable efficient construction Design elements are standardize Construction and procurement efficiency are specifications developed Design for modularization to facilitate fabrication/transportation Field Operation Contractors use innovative methods (Source: Tatum et.al; OConnor et.al; OConnor and Davis; (Eng, 2002)) CONSTRUCTABILITY PRINCIPLES BY CIIA For CIIA, they have review to the work of CII, and some developed construction information within the Australian context (Eng, 2002). At the beginning, they are 17 principles are being identified and tested. In the other hand, more than twenty of the personnel who experienced in construction are given feedback due to this tested. Through the test, Constructability Principles File (CIIA, 1992) has shown 12 concepts of constructability to represent current best practice applicable over five projects life cycle stages, which are feasibility studies stage, conceptual design stage, details design stage, construction stage and post construction stage (Eng, 2002). The twelve principles espoused were:- PRINCIPLESÂ  DESCRIPTION Integration Constructability must be made an integral part of project plan. Construction Knowledge Project planning must actively involve construction knowledge and experience. Team Skills Project team must be appropriate for the project based on their experience, skills and etc. Corporate Objectives Project team understanding against clients corporate and project objective to improve constructability. Available Resources Technology use in design solution must be matched with the skills and resources available. External factors External factors might affect the cost and program of the project. Program of project Overall project program must be realistic and have the commitment of the project team. Construction Methodology Construction methodology must be considered in project design. Accessibility Constructability will be improved if accessibility is considered good in the design stage of project. Specifications Constructability improved when efficiency considered in specification development. Construction innovation Constructability improved when innovation techniques is used Feedback Post construction analysis is undertaken to allow constructability can be enhanced on future projects Table Principles by CIIA (Francis and Sidwell (Eng, 2002)) CONSTRUCTABILITY CONCEPTS BY MALAYSIAN RESEARCHER According to Nawi, Kamar, Lee, Hamid, Abdullah, Haron and Ariff (2009), stated that in Malaysia, the constructability and buildability concepts established by the Construction Industry Institute (CII) and other relevant literature by CIRIA, (1983); Tatum, (1987); Adams, (1989); CII, (1993) and etc, there are 23 constructability concepts were formulated and presented by Nima, (2001) which use them to utilize a study in relation to the engineered construction phases. There are 7 concepts for conceptual planning phase, 8 concepts for design and procurement phase and 8 concepts for field operation phases which as follows:- C1-C7 (Project constructability enhancement during conceptual planning phase) Concept C1 the project constructability program should be discussed and documented within the project execution plan, through the participation of all project team members. Concept C2 a project team that includes representatives of the owner, engineer and contractor should be formulated and maintained to take the constructability issue into consideration from the outset of the project and through all of its phases. Concept C3 individuals with current construction knowledge and experience should achieve the early project planning so that interference between design and construction can be avoided. Concept C4 the construction methods should be taken into consideration when choosing the type and the number of contracts required for executing the project. Concept C5 the master project schedule and the construction completion date should be construction-sensitive and should be assigned as early as possible. Concept C6 in order to accomplish the field operations easily and efficiently, major construction methods should be discussed and analyses in-depth as early as possible to direct the design according to these methods. Concept C7 site layout should be studies carefully so that construction, operation and maintenance proceed efficiently and avoid any interference between the operations performed during these phases. C8-C15 (Project constructability enhancement during design and procurement phases) Concept C8 design and procurement schedules should be dictated by construction sequence. Thus, the construction schedule must be discussed and developed prior to the design development and procurement schedule. Concept C9 advanced information technologies are important to any field including field of construction industry. The usage of those technologies could overcome the problem of fragmentation into specialized roles in this field, hence enhancing constructability. Concept C10 designs, with design simplification by designers and design review by qualified construction personnel must be configured to enable efficient construction. Concept C11 project elements should be standardized to an extent that will never affect the project cost negatively. Concept C12 the project technical specifications should be simplified and configured to achieve efficient construction without sacrificing the level or the efficiency of the project performance. Concept C13 the implementation of modularization and preassembly for project elements should be taken into consideration and studied carefully. Modularization and preassembly design should be prepared to facilitate fabrication, transportation and installation. Concept C14 project design should take into consideration the construction personnel, materials and equipment accessibility to the required position on-site. Concept C15 design should facilitate construction during adverse weather conditions. Great emphasis should be made to planning for the construction of the project under suitable weather conditions, but the designer must plan and take into consideration the project elements that could be prefabricated in workshops. C16-C23 (Project constructability enhancement during field operation phases) Concept C16 field task sequencing should be configured in order to minimize damages or rework of some project elements, minimize scaffolding needs, formwork used or congestion of construction personnel, material and equipment. Concept C17 innovation in temporary construction materials/systems, or implementing innovative ways of using available temporary construction materials/systems that have not been defined or limited by the design drawings and technical specifications will contribute positively to the enhancement of constructability. Concept C18 incorporating innovation of new methods in using off-the-shelf hand tools or modification of the available tools or introduction of a new hand tools that may reduce labour intensity, increase mobility, safety or accessibility will enhance constructability at the construction phase. Concept C19 introduction of innovative methods for using the available equipment or modification of the available equipment to increase their productivity will lead to a better constructability. Concept C20 in order to increase the productivity, reduce the need of scaffolding or improve the project constructability under adverse weather conditions, constructors should be encouraged to use any optional preassembly. Concept C21 constructability will be enhanced by encouraging the constructor to carry out innovation of temporary facilities. Concept C22 good contractors, based on quality and time, should be documented, so that contracts for future construction works would not be awarded based on low bits only, but by considering other project attributes. Concept C23 evaluation, documentation and feedback of the issues of the constructability concepts should be maintained throughout the project to be used in later projects as lessons learned. (Source: Nima el al, (Nawi, et.al, 2009)) Although there are many researchers from different countries have identified and presented their own principles and concepts, but the points they covered are almost the same. Through those principles and concepts, it showing the ways to help the construction to reduce its project time, error, cost by having a good buildability on manage overall project. ASSESSMENT OF DESIGNS FOR BUILDABILITY According to CIRC and Chiang et.al, has stated that the construction industries are continues to search out the ways to improve buildability, such as the use of prefabricated, standardized and modular components, as well as the adoption of alternative procurement methods (cited by Wong, Lam, Chan P.C. and Chan H.W., 2006), the Building and Construction Authority (BCA) in Singapore had introduced and published a Code of Practice on Buildabl